6974-12-5Relevant articles and documents
Fourth subgroup metal complex with rigid annular bridging structure and application of fourth subgroup metal complex
-
Paragraph 0058; 0061; 0067, (2021/06/23)
The invention belongs to the technical field of olefin polymerization catalysts, and particularly relates to a fourth subgroup metal complex with a rigid annular bridging structure and an application of the fourth subgroup metal complex. The fourth subgroup metal complex provided by the invention has a structure represented by a formula (A) or a formula (B), X is halogen or alkyl; and M is titanium, zirconium or hafnium. On the basis of a non-metallocene catalyst, a bridging structure in catalyst molecules is improved and upgraded, and a brand-new metal complex with excellent catalytic performance and good high-temperature tolerance is designed; when the fourth subgroup metal complex is used as a main catalyst to catalyze olefin polymerization reaction, under the activation action of a small amount of mixed cocatalyst, the fourth subgroup metal complex can efficiently catalyze the copolymerization reaction of ethylene and alpha-olefin to obtain polyolefin with high molecular weight and high comonomer insertion rate.
Cross-metathesis of vinylsilanes carrying electron-withdrawing substituents with olefins in the presence of the second-generation Grubbs catalyst
Pietraszuk, Cezary,Marciniec, Bogdan,Fischer, Helmut
, p. 7121 - 7124 (2007/10/03)
The efficient cross-metathesis of vinylsilanes carrying electron-withdrawing substituents with various olefins is described. High yields and selectivities were obtained when styrene, 1-hexene, and selective functional allyl derivatives were used as the ol
Methyltrioxorhenium als Katalysator fuer die Olefin-Metathese
Herrmann, Wolfgang A.,Wagner, Werner,Flessner, Uwe N.,Volkhardt, Ursula,Komber, Hartmut
, p. 1704 - 1706 (2007/10/02)
-