69748-68-1Relevant academic research and scientific papers
Large Scale Synthesis of (+/-)-Isodrimenin and (+/-)-Confertifolin
Akita, Hiroyuki,Naito, Takanobu,Oishi, Takeshi
, p. 2166 - 2171 (2007/10/02)
Large scale syntheses of (+/-)-isodrimenin (4) and (+/-)-confertifolin (5) were achieved starting from β-ionone via the tricyclic furan derivative (16).Oxidation of this intermediate (16) with lead tetraacetate followed by pyrolysis afforded (+/-)-confertifolin (5) as a main product.Conversion of the lead tetraacetate oxidation product (17) into (+/-)-winterin (19) followed by NaBH4 reduction produced (+/-)-isodrimenin (4) as a main product.
