69765-64-6Relevant academic research and scientific papers
VICINAL ALKYLATION OF OLEFINS, REGIO- AND STEREOSELECTIVE ADDITION OF M + CN> UNITS TO CYCLOPENTADIENE.
Michel, P.,O'Donnell, M.,Biname, R.,Hesbain-Frisque, A.M.,Ghosez, L.,et al.
, p. 2577 - 2580 (2007/10/02)
Adducts of alkyl(phenylthio)ketenes to cyclopentadiene are cleaved with KOH-t-BuOK with retention of configuration at three centers.This observation broadens the synthetic potential of the method of vicinal alkylation of olefins.This method has been used for the vicinal addition of m + Cn> units to cyclopentadiene.
