697752-34-4Relevant academic research and scientific papers
Stereoselective synthesis of D-desosamine and related glycals via tungsten-catalyzed alkynol cycloisomerization
Davidson, Mary H.,McDonald, Frank E.
, p. 1601 - 1603 (2007/10/03)
Stereoselective synthesis of D-desosamine diacetate ester (iii, R = Ac) was achieved from the glycal (ii) generated by tungsten carbonyl-catalyzed cycloisomerization of the corresponding amino-alkynol (i). A wide variety of N-substituents (R, R′) are compatible with the cycloisomerization, provided that at least one R or R′ is an acyl derivative.
