69783-37-5

Upstream product

• 696-28-6 dichlorophenylarsine 
• 4451-96-1 diphenyl(trimethylsilylmethyl)phosphane 
• 712-48-1 chlorodiphenylarsine 
• 62263-69-8 (lithiomethyl)diphenylphosphane 

Downstream Products

• 108345-98-8 (Methyldiphenylarsonio)(methyldiphenylphosphonio)methan-bis(fluorsulfat) 
• 121289-43-8 fac-tricarbonylbis{((diphenylarsino)methyl)diphenylphosphane}molydenum 
• 121289-44-9 fac-{bis(diphenylphosphino)methane}tricarbonyl{((diphenylarsino)methyl)diphenylphosphane}molydenum 
• 88867-61-2 ((diphenylphosphino)(diphenylarsino)methane)dichloroplatinum(II) 
• 89144-43-4 cis-dichloro-bis((diphenylphosphino)(diphenylarsino)methane)platinum(II) 
• 96211-68-6 trans-bis((diphenylphosphino)(diphenylarsino)methane)carbonylchlororhodium(I) 
• 96211-62-0 ((diphenylphosphino)(diphenylarsino)methane)diiodoplatinum(II) 
• 96227-23-5 cis-diiodo-bis((diphenylphosphino)(diphenylarsino)methane)platinum(II) 
• 96211-63-1 cis-dibromo-bis((diphenylphosphino)(diphenylarsino)methane)platinum(II) 
• 96211-61-9 ((diphenylphosphino)(diphenylarsino)methane)dibromoplatinum(II) 
• 89741-90-2 Tetracarbonyl([(diphenylphosphino)methyl]diphenylarsoniummethylid-α-C,ω-P)chrom(0) 
• 89761-37-5 Tetracarbonyl([(diphenylarsino)methyl]diphenylphosphan-As,P)chrom⁽⁰⁾ 
• 89741-86-6 (CO)4CrAs(C₆H₅)2CH₂P(C₆H₅)2CH₂ 
• 97112-55-5 RhCOCl((C₆H₅)4CH₂AsP)2PtCl₂ 

Relevant academic research and scientific papers

Rearrangement and redistribution reaction of Ph2PCH2TMS with PhAsCl2 or AsCl3

The attempted synthesis of bis(diphenylphosphinomethyl) phenylarsane and tris(diphenylphosphinomethyl) arsane through condensation of chloro arsanes and diphenyl (trimethylsilylmethyl) phosphane yielded a number of side products originating from migratory and redox-reactions in addition to the targeted ligands. An unexpected, 1,3,4-phosphadiarssolan-1-ium salt was obtained and crystallographically characterized as an A-shaped chlorido adduct.

Transition Metal Complexes of Instable Ylides, III. Preparative, Stereochemical, and Mechanistic Aspects of the Stabilization of Instable Ylidic Chelate Ligands by Coordination to Chromium

The sulfur ylide complex (CO)5Cr (1) reacts with unsymmetrically substituted diphosphanes and arsanes of the type R21E1CH2E2R22 (4a-d) to give regioselectively the chelate complexes 5a-d.In 5 the more nucleophilic end of 4 is transformed to the onium centre.On the other hand, (CO)4Cr2 (2) and 4a-d produce regioselectively the isomeric chelate complexes 6a-d, in which the more nucleophilic donor function of 4 is ligated to the chromium atom.