69798-70-5Relevant articles and documents
Substrate-switched dual functionalization of alkenes: Catalyst-free synthetic route for β-hydroxy and β-keto thioethers
Badsara, Satpal Singh,Singh, Pratibha,Choudhary, Rakhee,Bai, Rekha,Sharma, Mahesh C.
supporting information, p. 11045 - 11049 (2019/07/31)
In this study, a substrate-controlled dual functionalization of alkenes under catalyst-free and solvent-free conditions is described. Alkenes possessing different electron-withdrawing groups, namely, ester and nitrile, reacted with a variety of thiols under air to provide β-hydroxy thioethers and β-keto thioethers, respectively, in good to excellent yields.
ELECTROREDUCTIVE CLEAVAGE OF CARBON-SULPHUR BONDS IN DITHIOACETALS
Itter, Nicola Schultz-von,Steckhan, Eberhard
, p. 2475 - 2484 (2007/10/02)
The carbon-sulphur bond in aliphatic diphenyldithioacetals, α-carbonyldiphenyldithioacetals and α-carbonylketene dimethyldithioacetals can be cleaved cathodically on mercury (Hg) or glassy carbon (GC) electrodes.In the presence of tetrabutylammoniumhydrog
Synthesis of α-Phenylthio Enones and Esters of α-Phenylthio Alkenoic Acids
Durman, John,Grayson, J.Ian,Hunt, Paul G.,Warren, Stuart
, p. 1939 - 1946 (2007/10/02)
The title compounds can be made by a Pummerer dehydration from the corresponding saturated sulphoxides.The alkylation of anions from saturated and unsaturated ketones is described.
REGIOSPECIFIC SYNTHESIS OF α-(PHENYLTHIO)KETONES VIA RHODIUM(II) ACETATE CATALYSED ADDITION OF THIOPHENOL TO α-DIAZOKETONES
McKervey, M. Anthony,Ratananukul, Piniti
, p. 2509 - 2512 (2007/10/02)
αα-Addition of thiophenol to α-diazoketones is catalysed efficiently by rhodium(II) acetate in benzene solution at room temperature, offering a convenient regiospecific route to a variety of α-(phenylthio)ketones.
REACTIONS OF PHENYLTHIOTRIMETHYISILYLMETHYLLITHIUM: PREPARATION OF α-PHENYLTHIOKETONES AND ADDITIONS TO 2-CYCLOHEXEN-1-ONE
Ager, David J.
, p. 2803 - 2806 (2007/10/02)
Phenylthiotrimethylsilylmethyllithium(1) was reacted with a variety of electrophiles, including some containing two functional groups. α-Phenylthioketones were obtained from the reaction with esters.The anion(1) underwent either 1,2- or 1,4-addition, depe
