69815-00-5Relevant academic research and scientific papers
Palladium-catalyzed methylation and arylation of sp2 and sp 3 C-H bonds in simple carboxylic acids
Giri, Ramesh,Maugel, Nathan,Li, Jiao-Jie,Wang, Dong-Hui,Breazzano, Steven P.,Saunders, Lindsey B.,Yu, Jin-Quan
, p. 3510 - 3511 (2007/10/03)
The use of preformed sodium carboxylates as substrates led to the first observation of facile Pd-insertions into sp3 β-C-H bonds in simple aliphatic acids. Consequently, Pd-catalyzed methylation and arylation of o-C-H bonds in benzoic acids and β-C-H bonds in aliphatic acids using either a phenylboronate, methylboronic acid, or ArI have been achieved via a C-H activation/C-C coupling sequence. Copyright
