698353-42-3

Basic information

• Product Name: Bicyclo[2.2.1]heptane-2,5-diamine, (1S,2S,4S,5S)- (9CI)
• Synonyms: Bicyclo[2.2.1]heptane-2,5-diamine, (1S,2S,4S,5S)- (9CI)
• CAS NO: 698353-42-3
• Molecular Formula: C₇H₁₄N₂
• Molecular Weight: 126.19946
• Product Categories: AMINEPRIMARY
• Mol File: 698353-42-3.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Bicyclo[2.2.1]heptane-2,5-diamine, (1S,2S,4S,5S)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.1]heptane-2,5-diamine, (1S,2S,4S,5S)- (9CI)(698353-42-3)
• EPA Substance Registry System: Bicyclo[2.2.1]heptane-2,5-diamine, (1S,2S,4S,5S)- (9CI)(698353-42-3)

Safety Data

• Hazardous Substances Data: 698353-42-3(Hazardous Substances Data)

Upstream product

• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 
• 698353-48-9 C₂₁H₂₆N₂ 
• 698353-40-1 (1S,2S,4S,5S)-2,5-bis[(4-methylphenyl)sulfonylamido]bicyclo[2.2.1]heptane 
• 171065-84-2 2,5-diaminobicyclo[2.2.1]heptane 
• 141737-16-8 rac-bicyclo[2.2.1]heptane-2,5-dione dioxime 
• 145092-68-8 (S,S)-bicyclo<2.2.1>heptane-2,5-dione 
• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 
• 5888-36-8 (1S,2R,4S,5R)-2,5-dihydroxybicyclo[2.2.1]heptane 

Downstream Products

• 539834-16-7 2,2'-[(1S,2S,4S,5S)-bicyclo[2.2.1]heptane-2,5-diylbis(nitrilomethylidyne)]bis(4,6-di-tert-butylphenol) 

Relevant articles and documents

Evaluation of the chiral DIANANE backbone as ligand for organolithium reagents

Novel endo,endo-2,5-diaminonorbonane-derived tertiary C2- symmetrical diamines were synthesized via the one-pot reductive amination of enantiomerically pure norbornane-2,5-dione. These ligands were applied to various catalytic reactions such as asymmetric deprotonation, asymmetric bromine-lithium exchange, and enantioselective addition of aryl- and allkylithium reagents to aromatic aldimines. Copyright

A highly enantioselective catalyst for the asymmetric Nozaki-Hiyama-Kishi reaction of allylic and vinylic halides

Catalytic asymmetric addition of vinylic halides and trifiates to aldehydes, with useful levels of stereoinduction, has been achieved for the first time using the salentype ligand (S,S)-5 (see scheme; PMB=para-methoxybenzyl), which contains the novel endo