698353-43-4Relevant academic research and scientific papers
Enantioselective Synthesis of DIANANE, a Novel C2-Symmetric Chiral Diamine for Asymmetric Catalysis
Berkessel, Albrecht,Schroeder, Michael,Sklorz, Christoph A.,Tabanella, Stefania,Vogl, Nadine,Lex, Johann,Neudoerfl, Joerg M.
, p. 3050 - 3056 (2007/10/03)
DIANANE (endo,endo-2,5-diaminonorbornane) is a novel chiral C 2-symmetric diamine, based on the rigid bicyclo[2.2.1]heptane scaffold. Schiff-base ligands derived from DIANANE have already found use in asymmetric catalysis, e.g., in the highly e
A highly enantioselective catalyst for the asymmetric Nozaki-Hiyama-Kishi reaction of allylic and vinylic halides
Berkessel, Albrecht,Menche, Dirk,Sklorz, Christoph A.,Schroeder, Michael,Paterson, Ian
, p. 1032 - 1035 (2007/10/03)
Catalytic asymmetric addition of vinylic halides and trifiates to aldehydes, with useful levels of stereoinduction, has been achieved for the first time using the salentype ligand (S,S)-5 (see scheme; PMB=para-methoxybenzyl), which contains the novel endo
