698379-54-3

Upstream product

• 82529-81-5 (E)-1-(1-((3,7-dimethylocta-2,6-dien-1-yl)oxy)methyl)-4-methoxybenzene 
• 824-94-2 p-methoxybenzyl chloride 
• 106-24-1 Geraniol 

Downstream Products

• 769936-19-8 2-[(1E,5E)-7-(4-Methoxy-benzyloxy)-1,5-dimethyl-hepta-1,5-dienyl]-2-methyl-[1,3]dithiane 
• 950598-33-1 (2E,6S,7Z,10R,11R,12S,14S)-6,10:14,15-diepoxy-11,12-isopropylidenedioxy-3,7,11,15-tetramethyl-1-(phenylthio)hexadeca-2,7-diene 
• 950598-45-5 C₃₁H₄₆O₆ 
• 950598-44-4 C₃₁H₄₅IO₆ 
• 950598-43-3 C₃₁H₄₆O₇ 
• 950598-32-0 (2E,5S,5R,7R,9Z,11S,14E)-7,11-epoxy-5,6-(isopropylidenedioxy)-16-(4-methoxybenzyloxy)-2,6,10,14-tetramethylhexadeca-2,9,14-trien-1-ol 
• 950598-42-2 C₂₈H₄₂O₆ 
• 950598-31-9 C₄₀H₇₀O₆Si₂ 
• 950598-39-7 C₂₉H₄₄O₇ 
• 950598-38-6 C₂₉H₄₄O₇ 
• 950598-37-5 C₃₅H₅₆O₇Si 
• 950598-36-4 tert-butyl (3R,4S,5S,7Z,9S,12E)-4,5-epoxy-3-hydroxy-14-(4-methoxybenzyloxy)-4,8,12-trimethyl-9-(triethylsiloxy)tetradeca-7,12-dienoate 
• 950598-30-8 tert-butyl (3S,4S,5S,7Z,9S,12E)-4,5-epoxy-3-hydroxy-14-(4-methoxybenzyloxy)-4,8,12-trimethyl-9-(triethylsiloxy)tetradeca-7,12-dienoate 

Relevant academic research and scientific papers

Total synthesis of methyl sarcophytoate

Together with the improved synthesis of the diene unit 15 of methyl sarcophytoate (1), a biscembranoid marine natural product, the asymmetric total synthesis of 1 was achieved by the thermal Diels-Alder reaction between the dienophile unit, methyl sarcoat

Oxidative deprotection of 1,3-dithiane group using NaClO2 and NaH2PO4 in aqueous methanol

The 1,3-dithiane group was oxidatively deprotected under the conditions of sodium chlorite, sodium dihydrogenphosphate, and 2-methyl-2-butene in 3:1 methanol-water at room temperature in good yield.