69857-02-9Relevant academic research and scientific papers
Reaction of Benzenesulfinyl Azide with Thiols and Amines. Preparation of Thiosulfinates and Sulfinamides
Maricich, Tom J.,Angeletakis, Christos N.
, p. 1931 - 1934 (2007/10/02)
Reaction of benzenesulfinyl azide (1) with thiols at -20 deg C gave thiosulfinates and hydrazoic acid.Reaction of 1 with primary and secondary amines gave sulfinamides and hydrazoic acid.The presence of a hydroxyl group in the thiol or amine did not change the course of the reaction.Thus, a thiosulfinate and sulfinamide containing a free hydroxyl group could be prepared.Yields ranging from 41percent to 93percent were obtained.
