69895-44-9Relevant articles and documents
(S)-dimethylsulfonium(p-tolylsulfinyl)methylide: A new chiral sulfonium ylide and its use in asymmetric epoxidation
Midura, Wanda H.
, p. 733 - 736 (2007/10/03)
The title optically active sulfonium ylide was prepared by methylation of easily available (-)-(S)-p-tolylmethylthiomethyl-sulfoxide and subsequent deprotonation. Its reaction with aldehydes gave α,β-epoxy sulfoxides with full enantioselectivity and moder
AN IMPROVED PROCEDURE FOR EFFICIENT GENERATION OF METHYL(OR p-TOLYL)THIOMETHYL GRIGNARD REAGENT AND ITS USE IN ORGANIC SYNTHESES
Ogura, Katsuyuki,Fujita, Makoto,Takahashi, Kazumasa,Iida, Hirotada
, p. 1697 - 1698 (2007/10/02)
The optimal condition for transformation of a chloromethyl sulfide into the corresponding Grignard reagent (2) in a high yield are established and 2 is shown to react with various functional groups such as an alkyl halide, an aldehyde, and a sulfinic este