699006-60-5Relevant academic research and scientific papers
Double Diastereoselective Approach to Chiral syn- and anti-1,3-Diol Analogues through Consecutive Catalytic Asymmetric Borylations
Pujol, Alba,Whiting, Andrew
, p. 7265 - 7279 (2017)
Homoallylic boronate carboxylate esters derived from unsaturated aldehydes via an imination, β-borylation, imine hydrolysis, and Wittig trapping sequence, were subjected to a second boryl addition to give 1,3-diborylated carboxylate esters. Control of the
One-pot catalytic asymmetric borylation of unsaturated aldehyde-derived imines; Functionalisation to homoallylic boronate carboxylate ester derivatives
Pujol, Alba,Calow, Adam D. J.,Batsanov, Andrei S.,Whiting, Andrew
supporting information, p. 5122 - 5130 (2015/05/13)
The β-borylation reaction of α,β-unsaturated aldehyde-derived imines, formed in situ, has been studied using a one-pot methodology, as a route to β-boryl aldehydes. The instability of the β-boryl aldehydes meant that derivatisation was required and routes
