699006-81-0Relevant academic research and scientific papers
One-pot catalytic asymmetric borylation of unsaturated aldehyde-derived imines; Functionalisation to homoallylic boronate carboxylate ester derivatives
Pujol, Alba,Calow, Adam D. J.,Batsanov, Andrei S.,Whiting, Andrew
, p. 5122 - 5130 (2015)
The β-borylation reaction of α,β-unsaturated aldehyde-derived imines, formed in situ, has been studied using a one-pot methodology, as a route to β-boryl aldehydes. The instability of the β-boryl aldehydes meant that derivatisation was required and routes
A selective transformation of enals into chiral γ-amino alcohols
Calow, Adam D. J.,Batsanov, Andrei S.,Pujol, Alba,Sole, Cristina,Fernandez, Elena,Whiting, Andrew
supporting information, p. 4810 - 4813 (2013/10/08)
A one-pot synthesis of chiral amino alcohols from α,β- unsaturated aldehydes is reported which circumvents competitive 1,2- versus 1,4-boryl addition, by means of using a sterically hindered amine-derived imine. In addition to the complete chemoselectivit
