699010-02-1Relevant academic research and scientific papers
Total Synthesis and Preliminary Biological Evaluation of cis-Solamin Isomers
Cecil, Alex R. L.,Hu, Yulai,Vicent, Maria J.,Duncan, Ruth,Brown, Richard C. D.
, p. 3368 - 3374 (2004)
An efficient total synthesis of cis-solamin (1) has been achieved in 21% overall yield and with a longest linear sequence of just 11 steps from aldehyde 8. A key feature of the approach was the use of asymmetric permanganate-promoted oxidative cyclization
Total synthesis and stereochemical assignment of cis-uvariamicin I and cis-reticulatacin
Abdel Ghani, Sherif B.,Chapman, James M.,Figadere, Bruno,Herniman, Julie M.,Langley, G. John,Niemann, Scott,Brown, Richard C. D.
supporting information; experimental part, p. 6924 - 6928 (2009/12/25)
(Graph Presented) Diastereoisomeric mixtures of cis-uvariamicin I (15R,16R,19S,20S,36S and 15S,16S,19R,20R,36S) and cis-reticulatacin (17R,18R,21S,22S,36S and 17S,18S,21R,22R,36S) were synthesized to determine the stereochemistry of the natural products i
