69930-77-4Relevant academic research and scientific papers
Synthesis of β-(Diphenylphosphinoyl) Ketones
Bell, Andrew,Davidson, Alan H.,Earnshaw, Chris,Norrish, Howard K.,Torr, Richard S.,et al.
, p. 2879 - 2892 (2007/10/02)
The title compounds may be made by addition of phosphorus nucleophiles (Ph2PO-, Ph2POMgX, Ph2PCl) to enones, by addition of phosphorus-stabilised carbanions to a α-carbonyl cation equivalents (2,3-dichloropropene, epoxides, and α-MeO-ketones) and by oxidation of allyl diphenylphosphine oxides.
Synthesis of Protected βγ-Unsaturated Ketones from β-Diphenylphosphinoyl Ketones
Earnshaw, Chris,Torr, Richard S.,Warren, Stuart
, p. 2893 - 2902 (2007/10/02)
Ketals of β-diphenylphosphinoyl ketones combine with aldehydes and ketones in the Horner-Wittig reaction to give ketals of βγ-unsaturated ketones.
