69971-20-6Relevant academic research and scientific papers
Acetoxy Meldrum's acid: A versatile acyl anion equivalent in the Pd-catalyzed asymmetric allylic alkylation
Trost, Barry M.,Osipov, Maksim,Kaib, Philip S. J.,Sorum, Mark T.
supporting information; experimental part, p. 3222 - 3225 (2011/08/07)
Acetoxy Meldrum's acid can serve as a versatile acyl anion equivalent in the Pd-catalyzed asymmetric allylic alkylation. The reaction of this nucleophile with various meso and racemic electrophiles afforded alkylated products in high yields and enantiopur
Biocatalytical Transformations- VI. The 4-Acetamido-cyclopent-2-ene Carboxylate Route Revisited: Synthesis of (+)- and (-)-Aristeromycin
Csuk, Rene,Doerr, Petra
, p. 5789 - 5798 (2007/10/02)
Enantiomerically pure (+)-as well as (-)-aristeromycin can be synthesized starting from (+)- or (-)-butyl (or hexyl) 4-acetamido-cyclopent-2-ene carboxylate; these carboxylates are easily obtained from their corresponding racemates by hydrolysis with the lipase from Candida rugosa.
