700367-73-3

Basic information

• Product Name: Butanal, 3-hydroxy-2,4-bis(phenylmethoxy)-, (2S,3S)-
• CAS NO: 700367-73-3
• Molecular Formula: C18H20O4
• Molecular Weight: 300.354
• Mol File: 700367-73-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Butanal, 3-hydroxy-2,4-bis(phenylmethoxy)-, (2S,3S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Butanal, 3-hydroxy-2,4-bis(phenylmethoxy)-, (2S,3S)-(700367-73-3)
• EPA Substance Registry System: Butanal, 3-hydroxy-2,4-bis(phenylmethoxy)-, (2S,3S)-(700367-73-3)

Safety Data

• Hazardous Substances Data: 700367-73-3(Hazardous Substances Data)

Upstream product

• 60656-87-3 benzyloxyacetoaldehyde 

Downstream Products

• 92206-12-7 (2R,3S)-2,4-bis(benzyloxy)butane-1,3-diol 

Relevant articles and documents

Plausible origins of homochirality in the amino acid catalyzed neogenesis of carbohydrates

The intrinsic ability of amino acids to catalyze the asymmetric formation of carbohydrates, which enzymes have mediated for millions of years, with significant amplification of enantiomeric excess suggests a plausible ancient catalytic process for the evo

Tertiary Amine Promoted Asymmetric Aldol Reaction of Aldehydes

The direct asymmetric self-aldol reactions of various α-oxyaldehydes catalyzed by tertiary amines have been demonstrated. By using 10 mol-% of quinine catalyst, dimerization products have been prepared in high yields, with good anti-diastereocontrol, and up to 80% ee. The presented enolate-mediated synthesis of protected tetrose sugars has never been accomplished before by chiral tertiary amine organocatalysts.

Direct amino acid catalyzed asymmetric synthesis of polyketide sugars

Back to the future: In a biomimetic asymmetric synthesis of sugars (see scheme) sequential cross-aldol reactions of simple aldehydes were catalyzed by amino acids. Deoxysugars were obtained with excellent chemoselectivity and up to > 99% ee. This transfor