70067-95-7Relevant academic research and scientific papers
THE USE OF METALLOIDS (-SiMe3,-SnR3) AS PROTECTED CARBANIONS; SELECTIVE ACTIVATION AND NEW CYCLIZATION PROCESSES
Andarsen, Niels H.,McCrae, David A.,Grotjahn, Douglas B.,Gabhe, Satish Y.,Theodore, Louis J.,et al.
, p. 4069 - 4079 (2007/10/02)
Two aspects of organosilicon and -tin chemistry will be dealt with in this paper: the reactivity of allylmetalloids and the potential of the C-MR3 function as a protected carbanion which can be unmasked to provide synthetically useful carbon nucleophiles with the primary focus on the latter.
Carbocyclizations employing 2-Silyl-1,3-dithians
Grotjahn, Douglas B.,Andersen, Niels H.
, p. 306 - 307 (2007/10/02)
Dithianyl anions capable of carbocyclization via either direct or Michael addition to a carbonyl unit can be generated from 2-trimethylsilyl-1,3-dithians.
