700834-74-8

Basic information

• Product Name: [Ge(N(Si(CH₃)3)2)2SC(O)CH₂O]
• Synonyms: [Ge(N(Si(CH₃)3)2)2SC(O)CH₂O]
• CAS NO: 700834-74-8
• Molecular Weight: 483.466
• Mol File: 700834-74-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ge(N(Si(CH₃)3)2)2SC(O)CH₂O](CAS DataBase Reference)
• NIST Chemistry Reference: [Ge(N(Si(CH₃)3)2)2SC(O)CH₂O](700834-74-8)
• EPA Substance Registry System: [Ge(N(Si(CH₃)3)2)2SC(O)CH₂O](700834-74-8)

Safety Data

• Hazardous Substances Data: 700834-74-8(Hazardous Substances Data)

Upstream product

• 700834-72-6 [(Et3P)2Pd(μ-S)(μ-CH2O)Ge(N(SiMe3)2)2] 
• 201230-82-2 carbon monoxide 

Relevant articles and documents

Sequential insertion of formaldehyde and carbon monoxide into a sulfide-bridged Pd-Ge bond followed by reductive elimination to form a [1,3,2] oxathiagermolan-4-one

The reaction of (Et3P)2Pd(μ-S)Ge[N(SiMe 3)2]2 (2) with paraformaldehyde under photolytic conditions results in the insertion of formaldehyde into the Pd-Ge bond, with bond cleavage, to give (Et3P)2Pd(μ-S) (μCH2O)Ge[N(SiMe3)2]2 (3). Subsequent addition of CO to 3 results in migratory insertion into the Pd-C bond, followed by rapid reductive elimination to regenerate the Pd0 metal center and give a unique five-membered organic heterocycle, Ge[N(SiMe 3)2]2-SC(O)CH2O (6). The X-ray crystal structure of the dppe (dppe = bis(diphenylphosphino)-ethane) derivative of 3, (dppe)Pd(μ-S)(μCH2O)Ge[N(SiMe3) 2]2 (4), is reported.