700870-92-4

Basic information

• Product Name: 5,6-dideoxy-1,2-O-isopropylidene-3-O-(4-methoxybenzyl)-6-C-phenyl-α-D-galactofuranose
• Synonyms: 5,6-dideoxy-1,2-O-isopropylidene-3-O-(4-methoxybenzyl)-6-C-phenyl-α-D-galactofuranose
• CAS NO: 700870-92-4
• Molecular Weight: 384.472
• Mol File: 700870-92-4.mol

Chemical Properties

• CAS DataBase Reference: 5,6-dideoxy-1,2-O-isopropylidene-3-O-(4-methoxybenzyl)-6-C-phenyl-α-D-galactofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 5,6-dideoxy-1,2-O-isopropylidene-3-O-(4-methoxybenzyl)-6-C-phenyl-α-D-galactofuranose(700870-92-4)
• EPA Substance Registry System: 5,6-dideoxy-1,2-O-isopropylidene-3-O-(4-methoxybenzyl)-6-C-phenyl-α-D-galactofuranose(700870-92-4)

Safety Data

• Hazardous Substances Data: 700870-92-4(Hazardous Substances Data)

Upstream product

• 700870-90-2 (3aR,6aR)-2,2-Dimethyl-5-phenethyl-3a,6a-dihydro-furo[2,3-d][1,3]dioxole 
• 137585-73-0 5,6-dideoxy-1,2-O-(isopropylidene)-6-phenyl-α-D-xylo-hexofuranose 
• 2746-25-0 p-Methoxybenzyl bromide 
• 700870-91-3 5,6-dideoxy-1,2-O-(isopropylidene)-6-phenyl-β-L-arabino-hexofuranose 

Downstream Products

• 700870-94-6 (2S,3S)-2-(4-methoxybenzyloxy)-3-formyloxy-5-phenyl-1-pentanal 

Relevant articles and documents

Facile One-Step Synthesis of β-Alkoxy Lactone via Sequential Lactonization and 1,4-Addition of Alkoxide Group: Total Synthesis of All Stereoisomers of Dihydrokawain-5-ol

We describe here a divergent total synthesis of all of the four stereoisomers of dihydrokawain-5-ol starting from α-D-glucose. The approach involves the use of Ando's modification of Horner-Wadsworth-Emmons homologation to give a α,β-unsaturated ester. Subsequently, lactonization and 1,4-addition of OMe group in one step provided a γ-lactone, which was converted into the target compounds in two steps.