70090-71-0

Usage

General Description

1,1'-Biphenyl, 4-(2-propynyl)- is a chemical compound that consists of a biphenyl molecule with a propynyl group attached to the 4-position of one of the benzene rings. It is commonly used in organic synthesis as a building block for the construction of more complex molecules. 1,1'-Biphenyl, 4-(2-propynyl)- has a variety of applications, including as a starting material for the synthesis of pharmaceuticals, agrochemicals, and materials science. It is also used in the production of liquid crystals and dyes. Additionally, 1,1'-Biphenyl, 4-(2-propynyl)- has been studied for its potential use in the development of novel materials and as a reagent in organic chemistry reactions.

Upstream product

• 61502-90-7 4-Biphenylacetaldehyde 
• 31603-77-7 4-biphenylacetonitrile 
• 30265-81-7 1-(4-phenylphenyl)-2-propyn-1-ol 

Downstream Products

• 515869-53-1 tert-butyl 4-[6-(3-biphenyl-4-yl-prop-1-ynyl)-1-methyl-2,4-dioxo-1,4-dihydro-2H-quinazolin-3-ylmethyl]-benzoate 
• 220211-94-9 5-phenyl-1H-inden-2(3H)-one 
• 61948-01-4 4-(1-Propynyl)biphenyl 

Relevant academic research and scientific papers

Ruthenium-Catalyzed Propargylic Reduction of Propargylic Alcohols with Hantzsch Ester

Ruthenium-catalyzed propargylic reduction of propargylic alcohols bearing a terminal alkyne moiety is accomplished by using Hantzsch ester as a nucleophilic hydride source. A variety of secondary and tertiary propargylic alcohols are reduced to the corresponding propargylic reduced products such as 1-alkynes in excellent yields. Some mechanistic studies indicate that ruthenium-allenylidene complexes may work as key reactive intermediates.

Biarylphosphonite gold(I) complexes as superior catalysts for oxidative cyclization of propynyl arenes into indan-2-ones

Striking gold: A series of variously functionalized propynyl arenes was smoothly converted into indan-2-ones by a new gold(I)-catalyzed oxidative cyclization process. [LAu]NTf2 (Tf=trifluoromethanesulfonyl) is a superior catalyst both in terms of yield and kinetics for the present transformation. Copyright

Preparation of thiolate-bridged dinuclear ruthenium complexes bearing a phosphine ligand and application to propargylic reduction of propargylic alcohols with 2-propanol

Novel thiolate-bridged dinuclear ruthenium complexes bearing a phosphine ligand, [CpRu{PhP(C6H4-o-S)2}RuCp](OTf) 2, [CpRu{PhP(C6H4-o-S)2}RuCp(OH 2)](OTf)2, and [CpFe{PhP(C6H 4-o-S)2}RuCp](OTf)2, are prepared and characterized by X-ray analysis. These dinuclear complexes work as effective catalysts toward propargylic reduction of propargylic alcohols with 2-propanol via allenylidene complexes as key intermediates to give the corresponding alkynes in good to high yields.

Alkynylated fused ring pyrimidine compounds

A compound selected from those of formula (I): wherein W1 represents O, S, or —NR3 in which R3 represents hydrogen, alkyl, OH or CN; W2 represents a group selected from hydrogen, CF3, NH2,