70101-34-7Relevant academic research and scientific papers
NEMATICIDE COMPOUNDS, COMPOSITIONS, AND METHODS OF THEIR MAKING AND USE
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Paragraph 0152; 0362; 0364; 0368, (2022/01/24)
The present application relates to compounds of formulae (I)-(VII) as defined herein, compositions containing these compounds, methods of their use, and methods of making. The compounds have nematacide activity.
N-Heterocyclic carbene-catalyzed stereoselective construction of olefinic carbon-sulfur bonds: Via cross-coupling reaction of gem-difluoroalkenes and thiols
Cong, Zi-Song,Li, Yang-Guo,Chen, Lei,Xing, Fen,Du, Guang-Fen,Gu, Cheng-Zhi,He, Lin
supporting information, p. 3863 - 3868 (2017/07/11)
A novel organocatalytic olefinic carbon-sulfur bond forming reaction was developed. Under the catalysis of 10 mol% stable N-heterocyclic carbene, thiols undergo direct nucleophilic substitution reaction with gem-difluoroalkenes to produce α-fluorovinyl thioethers in high yields with excellent Z-selectivity. In this process, bases are not necessary.
