7011-06-5

Upstream product

• 108-24-7 acetic anhydride 
• 169529-93-5 (-)-2,3-dibromocyclohex-5-ene-1,4-diol 
• 80582-73-6 (1S,2R,3S,6S)-2-bromo-7-oxabicyclo[4.1.0]hept-4-en-3-ol 
• 251538-17-7 (1S,2R,3S,6R)-6-azido-2-bromocyclohex-4-ene-1,3-diol 
• 639079-42-8 (1R,2S,3S,4R)-1-azidoconduritol B 
• 639799-16-9 (1R,2S,3S,4R)-2,3,4-tri-O-acetyl-1-azidoconduritol B 
• 639079-54-2 (+)-1,5,6-tri-O-acetyl-4-azido-myo-inositol 
• 639799-29-4 (-)-1,2,3,5,6-penta-O-acetyl-4-deoxy-4-azido-myo-inositol 
• 31077-18-6 1,2,3,4,5,-penta-O-acetyl-6-bromo-6-deoxy-scyllo-inositol 
• 488-53-9 (+/-)-6t-amino-cyclohexane-1r,2c,3c,4t,5c-pentaol 
• 488-53-9 (+/-)-6c-amino-cyclohexane-1r,2c,3c,4t,5c-pentaol 
• 64288-00-2 trans-cyclohexa-3,5-diene-1,2-diyl diacetate 
• 77804-07-0 r-(p-Chloracetanilido)-2-cyclohexen-c-4,t-5,c-6-triyltriacetat 
• 78775-99-2 2-Oxa-3-azabicyclo<2.2.2>-5-octen-7-exo-8-endo-diyldiacetat-hydrochlorid 

Downstream Products

• 3613-86-3 (+/-)-2-acetylamino-2-deoxy-epi-inositol 

Relevant academic research and scientific papers

Stereoselective synthesis of several azido/amino- and diazido/diamino-myo-inositols and their phosphates from p-benzoquinone

A practical route is described for the preparation of azido-myo-inositols, amino-myo-inositols and azido-conduritol B derivatives. Starting from p-benzoquinone, optically pure compounds in both forms can be prepared via enzymatic resolution of a derived diacetoxy conduritol B derivative. Selective introduction of nitrogen-containing functional groups in four of the six possible positions in the cyclitol moiety is followed by further functionalization to yield the target compounds.

Polyhydroxyamino Compounds via Diene Synthesis with Nitroso Compounds, VI. - Syntheses of Inosamine Derivatives

With trans-6-methoxy-1,3-cyclohexadiene-5,6-diyldiacetate or -5,6-diol inosamine derivatives are synthesized in good yield.

Polyhydroxyamino Compounds via Diene Synthesis with Nitroso Compounds, VII. - Synthesis of Conduramine-F1

A two-step synthesis of conduramine-F1 with trans-1,3-cyclohexadien-5,6-diyldiacetat (1) as educt is described.

Conversion of 1,6-Anhydromaltose into Pseudodisaccharides Containing Aminocyclitols as Constituent

1,6-Anhydromaltose was chemically converted into a couple of pseudodisaccharides containing different inosamine (3-amino-3-deoxy-epi- and 1-amino-1-deoxy-1 L-myo-inositol) residues as constituents via 6-deoxy-6-nitro-maltose derivatives.

Synthetic Study and Conformational Analysis of O-Benzylated Aminocyclitols

DL-(1,3/2)-3-Acetamido-1,2-di-O-benzylcyclohex-4-enediol (IIIa) and DL-(1,3/4)-1-acetamido-3,4-di-O-benzylcyclohex-5-enediol (IIIb) were synthesized from DL-trans-1,2-di-O-benzylcyclohex-3-enediol (I) via the corresponding azide derivatives (IIa-b) prepar