70117-00-9Relevant articles and documents
Synthetic Studies on Enantioselective Total Synthesis of Cyathane Diterpenoids: Cyrneines A and B, Glaucopine C, and (+)-Allocyathin B2
Wu, Guo-Jie,Zhang, Yuan-He,Tan, Dong-Xing,He, Long,Cao, Bao-Chen,He, Yu-Peng,Han, Fu-She
, (2019/03/19)
The details for the synthetic studies on enantioselective total synthesis of cyathane diterpenoids cyrneine A (1) and B (2), glaucopine C (3), and (+)-allocyathin B2 are presented. We established a mild Suzuki coupling for heavily substituted n
Total synthesis of (+)-allocyathin B2
Trost, Barry M.,Dong, Li,Schroeder, Gretchen M.
, p. 2844 - 2845 (2007/10/03)
The first enantioselective synthesis of (+)-allocyathin was achieved. The synthesis features a Pd-catalyzed asymmetric allylic alkylation to install the first quaternary center, a Ru-catalyzed diastereoselective cycloisomerization to construct the six-mem
Exploiting the Pd- and Ru-catalyzed cycloisomerizations: Enantioselective total synthesis of (+)-allocyathin B2
Trost, Barry M.,Dong, Li,Schroeder, Gretchen M.
, p. 10259 - 10268 (2007/10/03)
Pd- and Ru-catalyzed cycloisomerizations of 1,6-enynes are compared and contrasted. Such considerations led to the enantioselective synthesis of a cyathin terpenoid, (+)-allocyathin B2 (1). The synthesis features a Pd-catalyzed asymmetric allyl
Synthetic studies on cyathins: Enantioselective total synthesis of (+)-allocyathin B2
Takano, Masashi,Umino, Akinori,Nakada, Masahisa
, p. 4897 - 4900 (2007/10/03)
(Chemical Equation Presented) The enantioselective total synthesis of (+)-allocyathin B2 has been achieved. Our approach features a convergent enantioselective construction of the 5-6-7 tricyclic core system using the originally developed chira
