7012-95-5Relevant academic research and scientific papers
Copper-catalyzed redox-neutral C-H amination with amidoximes
Chen, Hui,Chiba, Shunsuke
supporting information, p. 42 - 46 (2014/01/06)
CuI-catalyzed reactions of N-alkylamidoximes afforded dihydroimidazoles via sp3 C-H amination. On the other hand, the reactions of N-benzoylamidoximes resulted in sp2 C-H amination to form quinazolinones. The reaction mechanisms could be characterized as a redox-neutral radical pathway including a Cu(i)-Cu(ii) redox catalytic cycle. The Royal Society of Chemistry.
