701255-93-8

Basic information

• Product Name: Os(OH)2ClNO(P(C₆H₅)3)2
• CAS NO: 701255-93-8
• Molecular Weight: 814.255
• Mol File: 701255-93-8.mol

Chemical Properties

• CAS DataBase Reference: Os(OH)2ClNO(P(C₆H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: Os(OH)2ClNO(P(C₆H₅)3)2(701255-93-8)
• EPA Substance Registry System: Os(OH)2ClNO(P(C₆H₅)3)2(701255-93-8)

Safety Data

• Hazardous Substances Data: 701255-93-8(Hazardous Substances Data)

Upstream product

• 189028-09-9 OsClCOOONO(P(C₆H₅)3)2 
• 7732-18-5 water 

Relevant articles and documents

Dioxygen oxidation of a carbonyl ligand to form a chelating peroxycarbonyl ligand: Synthesis, structure, and reactions of Os(C[O]OO)Cl(NO)](PPh 3)2

Reaction between the carbonyl, nitrosyl complex, OsCl(CO)(NO)(PPh 3)2 (1) and dioxygen results in combination of CO and O2, forming a chelating peroxycarbonyl ligand in the yellow complex, Cl(NO)(PPh3)2 (2). Confirmation of the unique peroxycarbonyl ligand arrangement in 2 is provided by crystal structure determination. When 2 is heated, as a suspension in heptane under reflux, there is a rearrangement to the regular chelating carbonate ligand in the orange complex, Cl(NO)(PPh3)2 (3). The structure of 3 has also been determined by X-ray crystallography. Compound 2 also undergoes the following reactions: with water, releasing CO2 and forming Os(OH)2Cl(NO)(PPh3)2 (4); with HCl releasing CO2 and forming Os(OH)Cl2(NO)(PPh3) 2 (5); and with excess triphenylphosphine releasing CO2 and triphenylphosphine oxide forming OsCl(NO)(PPh3)3 (6).