70187-44-9 Usage
General Description
3-Fluoro-3-nitrooxetane is a chemical compound with the molecular formula C3H4FNO4. It is a highly reactive and explosive organic compound that is used in the synthesis of various pharmaceuticals and agrochemicals. The compound has a nitrooxetane functional group which makes it highly reactive and unstable. Due to its explosive nature, it requires careful handling and storage. 3-Fluoro-3-nitrooxetane has the potential for use in high-energy materials and as a building block in the synthesis of complex organic compounds. Its unique properties make it a valuable tool for chemical researchers and engineers.
Check Digit Verification of cas no
The CAS Registry Mumber 70187-44-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,0,1,8 and 7 respectively; the second part has 2 digits, 4 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 70187-44:
(7*7)+(6*0)+(5*1)+(4*8)+(3*7)+(2*4)+(1*4)=119
119 % 10 = 9
So 70187-44-9 is a valid CAS Registry Number.
InChI:InChI=1/C3H4FNO3/c4-3(5(6)7)1-8-2-3/h1-2H2
70187-44-9Relevant articles and documents
Reactions of 2-Fluoro-2-nitro-1,3-propanediol. Trifluoromethanesulfonates and 3-Fluoro-3-nitrooxetane
Berkowitz, Phillip T.,Baum, Kurt
, p. 4853 - 4857 (1980)
The reaction of diethyl fluoronitromalonate with base and formaldehyde provided a convenient synthesis of 2-fluoro-2-nitro-1,3-propanediol.This diol reacted with triflic anhydride to give 2-fluoro-3-hydroxy-2-nitro-1-propyl triflate and 2-fluoro-2-nitro-1,3-propylene ditriflate.The monotriflate reacted with base to give 3-fluoro-3-nitrooxetane.The ditriflate underwent displacement reactions with sodium azide, 2-fluoro-2,2-dinitroethanol, and methanol.Reactions of 3-fluoro-3-nitrooxetane with strong acids resulted in ring opening to give 3-substituted 2-fluoro-2-nitropropanols.The oxetane was polymerized with phosphorus pentafluoride.Triflates derived from 2,2-dinitro-1,3-propanediol and 2-(hydroxymethyl)-2-nitro-1,3-propanediol did not cyclize.
