70187-96-1Relevant academic research and scientific papers
Electrochemical oxyphenylselenation of dienes
Vukicevic, Rastko D.,Radovic, Milos,Konstantinovic, Stanimir
, p. 1309 - 1312 (2007/10/03)
The electrochemical oxidation of diphenyl diselenide in the presence of dienes affords the corresponding cyclic β-phenylselenoethers via an oxyphenylselenation process. The yields of ethers depend on the nature of the diene and on the reaction temperature
PHENYLSELENENYL CHLORIDE IN ACETONITRILE-WATER; A HIGHLY CONVENIENT REAGENT FOR HYDROXYSELENATION OF OLEFINS AND PREPARATION OF CYCLIC ETHERS FROM DIENES
Toshimitsu, Akio,Aoai, Toshiaki,Owada, Hiroto,Uemura, Sakae,Okano, Masaya
, p. 5301 - 5306 (2007/10/02)
The reaction of phenylselenenyl chloride with olefins in aqueous acetonitrile affords β-hydroxyalkyl phenyl selenides in excellent yields, providing the most convenient method for hydroxyselenation of olefins so far reported.When the reaction was applied to conjugated dienes, monohydroxyselenated products were obtained in good to excellent yields.From non-conjugated dienes, on the other hand, cyclic ethers containing two phenylseleno groups were produced in good to excellent yields, the first step of this reaction being the hydroxyselenation of one double bond.
