702-99-8Relevant academic research and scientific papers
Synthesis and characterization of novel carbene complexes of phosphorus(V) fluorides with potential liquid-crystalline properties
Pajkert, Romana,B?ttcher, Tobias,Ponomarenko, Maksym,Bremer, Matthias,R?schenthaler, Gerd-Volker
, p. 8943 - 8951 (2013/09/23)
A series of novel push-push I and push-pull II carbene-stabilized complexes of phosphorus(V) fluorides bearing substituents with liquid-crystalline properties were synthesized by the oxidative addition of difluoroamines to phosphorus(III) halides. These octahedral complexes were characterized by NMR spectroscopy and X-ray analysis.
Phosphorus(V) complexes with acyclic monoaminocarbene ligands via oxidative addition
B?ttcher, Tobias,Bassil, Bassem S.,Zhechkov, Lyuben,R?schenthaler, Gerd-Volker
supporting information, p. 5651 - 5653 (2013/07/04)
(Difluoroorganyl)dimethylamines, RCF2NMe2 (R = H, Ph, tBu), can be used as carbene precursors for phosphorus trifluoride in an oxidative addition reaction. By this method, complexes of sterically nondemanding asymmetric and acyclic c
Fluorination of thiocarbon compounds with bis(2-methoxyethyl)aminosulfur trifluoride (deoxo-fluor reagent): A facile synthesis of gem-difluorides
Lal, Gauri S.,Lobach, Elyse,Evans, Ann
, p. 4830 - 4832 (2007/10/03)
A variety of thiocarbonyl derivatives (thioketone, thioester, thioamide, dithioester, and dithiocarbamate) were converted to the corresponding gem-difluorides in excellent yields on reaction with the fluorinating agent, bis(2-methoxyethyl)aminosulfur trif
REACTIONS OF N,N-DIALKYLBENZAMIDES WITH SULFUR TETRAFLUORIDE. FORMATION OF DIALKYL-α,α-DIFLUOROBENZYLAMINES
Dmowski, Wojciech,Kaminski, Maciej
, p. 1369 - 1378 (2007/10/02)
N,N-Dialkylbenzamides (1 and 3) react with sulfur tetrafluoride in presence of potassium fluoride to afford dialkyl-α,α-difluorobenzylamines (2 and 4) in good yields.The effects of the reactant structures and reaction conditions on the yield of products h
