70250-34-9Relevant academic research and scientific papers
Symmetrical spiro-phosphoroheterocycles from the selenation of carbohydrazides
Hua, Guoxiong,Cordes, David B.,Li, Yang,Slawin, Alexandra M.Z.,Derek Woollins
, p. 3311 - 3314 (2011)
2,4-Bis(phenyl)-1,3-diselenadiphosphetane-2,4-diselenide (Woollins' reagent) reacts with benzoic hydrazides in refluxing toluene to give new symmetrical spiro heterocycles in 48-76% isolated yields. However, under identical conditions, treating Woollins' reagent with thiophene-2-carbohydrazide leads to an additional product, 1,3,4-selenadiazole (27% yield) together with the spiro phosphorus heterocycle in 44% yield. Three representative X-ray structures are reported.
