70277-91-7Relevant academic research and scientific papers
15N Nuclear Polarisation in Nitration and Related Reactions. Part 8. The Mechanisms of Rearrangement of 2-Methyl-2-nitrocyclohexa-3,5-dienones
Ridd, John H.,Trevellic, Susan,Sandall, John P. B.
, p. 1073 - 1079 (2007/10/02)
A kinetic study has been carried out on the regiospecific rearrangement of 2-methyl-2-nitrocyclohexa-3,5-dienone to 2-methyl-6-nitrophenol in acetic anhydride containing 0.2percent sulfuric acid at -27.8 to -6.5 deg C.Related studies have been carried out
Evidence from (15)N Nuclear Polarisation on the Mechanisms of Rearrangement of Nitrocyclohexadienones
Ridd, John H.,Sandall, John P. B.,Trevellick, Susan
, p. 1195 - 1196 (2007/10/02)
Strong (15)N nuclear polarisation is present in both the uncatalysed and acid-catalysed rearrangements of 4-methyl-4-cyclohexa-2,5-dienone but is absent from the rearrangement of 2-methyl-2-nitrocyclohexa-3,5-dienone.
