70302-37-3

Basic information

• Product Name: (S)-2-(2-Oxo-propyl)-cyclohexanecarboxylic acid
• CAS NO: 70302-37-3
• Molecular Weight: 184.235
• Mol File: 70302-37-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-2-(2-Oxo-propyl)-cyclohexanecarboxylic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-(2-Oxo-propyl)-cyclohexanecarboxylic acid(70302-37-3)
• EPA Substance Registry System: (S)-2-(2-Oxo-propyl)-cyclohexanecarboxylic acid(70302-37-3)

Safety Data

• Hazardous Substances Data: 70302-37-3(Hazardous Substances Data)

Upstream product

• 2695-47-8 6-Bromo-1-hexene 
• 128488-52-8 (6S,7S,10R)-3-(5-hexenyl)-7-isopropyl-2,10-dimethyl-4-oxo-1,5-dioxaspiro<5.5>undec-2-ene 
• 128488-46-0 t-butyl 2-acetyl-5-octenoate 
• 128488-60-8 (1S,2'S,3S,5S,5'R,8R)-3-methyl-7-oxo-4,6-dioxatricyclo<6.4.0.0^3.8>dodecane-5-spiro(2'-isopropyl-5'-methyl)cyclohexane 
• 128488-49-3 3-(5-hexenyl)-2-methyl-4-oxo-1,5-dioxaspiro<5.5>undec-2-ene 
• 128488-55-1 3-methyl-7-oxo-4,6-dioxatricyclo<6.3.0.0^3.8>dodecane-5-spirocyclohexane 

Downstream Products

• 128572-45-2 (Z)-2-acetonylcyclohexanecarboxylate 
• 128572-44-1 (E)-2-acetonylcyclohexanecarboxylate 
• 58706-96-0 (1S,2R)-2-(2-Oxo-propyl)-cyclohexanecarboxylic acid methyl ester 
• 58706-96-0 methyl cis-2-(2-oxopropyl)cyclohexane-1-carboxylate 

Relevant articles and documents

Use of 1,3-Dioxin-4-ones and Their Related Compounds in Synthesis. Part 28 . Asymmetric de Mayo Reactions Using Chiral Spirocyclic Dioxinones

The use of rigid spirocyclic dioxinones having 1-menthone as the chiral auxiliary as the enones in the photocycloaddition reactions opened novel methods for obtaining enantiomerically pure compounds, such as iridoids.Convex side preference of the sofa-conformation of these dioxinones in the photoaddition to cyclopentene increases up to 100percent by introducing either a bulky substituent or 5-hexenyl group at the 3-position to these dioxinones and, hence, highly asymmetric inter- and intramolecular de Mayo reactions have been disclosed.