70329-89-4

Upstream product

• 82262-29-1 5-hydroxy-1,3-dimethyltricyclo<4.3.1.0^3,7>decan-9-one 2,2-dimethylpropylene acetal 
• 82262-27-9 9-diethoxyphosphoryloxy-1,3-dimethyltricyclo<4.3.1.0^3,7>dec-8-en-5-ol 
• 82262-30-4 5-hydroxy-5-isopropenyl-1,3-dimethyltricyclo<4.3.1.0^3,7>decan-9-one 2,2-dimethylpropylene acetal 
• 82268-20-0 1,3-dimethyltricyclo<4.3.1.0^3,7>decan-5,9-dione 9-(2,2-dimethylpropylene) acetal 
• 70329-78-1 5-hydroxy-1,3-dimethyltricyclo<4.3.1.0^3,7>decan-9-one 
• 70329-74-7 5-isopropenyl-1,3-trimethyltricyclo<4.3.1.0^3,7>dec-4-en-9-one 

Relevant academic research and scientific papers

A Total Synthesis of (+/-)-9-Pupukeanone

A stereoselective total synthesis of (+/-)-9-pupukeanone (3), an intermediate employed in previously reported total syntheses of the structurally novel sesquiterpenoid (+/-)-9-isocyanopupukeanane (1), is described.In the key step of the synthetic sequence

Total Synthesis of (+/-)-9-Pupukeanone

A synthesis of (+/-)-9-pupukeanone (3) is described in which the pupukeanane skeleton is assembled by means of an intramolecular Diels-Alder reaction of 20 to 21.The vinyl ketone 20 was constructed via a sequence beginning from 8 and proceeding through di