70347-50-1

Upstream product

• 81266-62-8 Benzoic acid (2R,3aR,6aS)-1-(tert-butyl-dimethyl-silanyloxymethyl)-5-oxo-octahydro-pentalen-2-yl ester 
• 81266-61-7 (3aS,5R,6aR)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-5-hydroxy-hexahydro-pentalen-2-one 
• 97419-64-2 Benzoic acid (1R,2S,3aR,6aS)-1-(tert-butyl-diphenyl-silanyloxymethyl)-5-oxo-4,4-bis-phenylsulfanyl-octahydro-pentalen-2-yl ester 
• 97419-65-3 3-endo-benzoyloxy-2-exo-(t-butyldiphenylsilyloxymethyl)-7-oxobicyclo<3.3.0>octane 
• 81266-59-3 Benzoic acid (3aR,5R,6aS)-4-(tert-butyl-dimethyl-silanyloxymethyl)-2-[1-ethoxycarbonyl-meth-(E)-ylidene]-hexahydro-cyclopenta[b]furan-5-yl ester 
• 64982-34-9 Benzoic acid (3aR,5R,6aS)-4-(tert-butyl-dimethyl-silanyloxymethyl)-2-oxo-hexahydro-cyclopenta[b]furan-5-yl ester 
• 79745-55-4 [(3aR,6aS)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-5-oxo-hexahydro-cyclopenta[b]furan-(2E)-ylidene]-acetic acid ethyl ester 
• 79745-54-3 [(3aR,5R,6aS)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-5-hydroxy-hexahydro-cyclopenta[b]furan-(2E)-ylidene]-acetic acid ethyl ester 
• 79745-56-5 (3aS,5R,6aS)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-5-hydroxy-2-oxo-octahydro-pentalene-1-carboxylic acid ethyl ester 
• 39746-00-4 Benzoic acid (3aR,5R,6aS)-4-hydroxymethyl-2-oxo-hexahydro-cyclopenta[b]furan-5-yl ester 

Downstream Products

• 97419-66-4 3-endo-benzoyloxy-2-exo-(1,3-diphenyl-1,3,2-diazaphospholan-2-yloxymethyl)-7-oxobicyclo<3.3.0>octane 

Relevant academic research and scientific papers

Functionalised Carbocycles from Carbohydrates. Part 7. A Route to Carbacyclin from a D-Glucose Derivative. X-Ray Crystal Structure of 3-endo-Benzoyloxy-2-exo-(1,3-diphenyl-1,3,2-diazaphospholan-2-yloxymethyl)-6-oxobicyclooctane

A specific method for converting the epoxide (7), which was previously obtained from methyl α-D-glucopyranoside, into the prostaglandin intermediate (1) is described, and a route from this latter compound into the previously reported bicyclooctan-3