70353-91-2Relevant academic research and scientific papers
ACTION DU METHYLTRI(N-BUTYL)FLUOROPHOSPHORANE SUR LES HALOGENURES ET LES SULFONATES D'ALKYLE
Leroy, J.,Bensoam, J.,Humiliere, M.,Wakselman, C.,Mathey, F.
, p. 1931 - 1936 (2007/10/02)
Monofluorophosphoranes R3MePF are used in exchange reactions to prepare monofluorinated organic compounds.Tri(n-butyl)methylfluorophosphorane (n-Bu3MePF), easily available, is the most reactive.In solvents of low polarity or even in non-polar solvents, it reacts at -70 deg C with alkyl sulphonates and halides activated by ester, ketone, or ether functions.Thus, fluorinated epoxides can be obtained directly by exchange from their chlorinated or brominated homologues.
