70367-72-5Relevant academic research and scientific papers
THE C-ALKYLATION OF NITROALKANE ANIONS BY 1-SUBSTITUTED-2-T-BUTYL-4-PHENYL- AND -2,4-DIPHENYL-5,6-DIHYDROBENZOQUINOLINIUM CATIONS.
Katritzky, Alan R.,Kashmiri, M. Akram,Wittmann, Dieter K.
, p. 1501 - 1510 (2007/10/02)
The N-substituents are transferred from the title cations to the C-atom of nitroalkane anions in high yield at 25-80 deg C in DMSO solution.The title cations are readily available from the appropriate pyrylium cations and primary amines of types RCH2NH2 and RR'CHNH2, allowing a general 2-step method for the preparation of higher nitroalkanes.Spectral properties of a variety of nitroalkanes are discussed.
NUCLEOPHILIC SUBSTITUTION IN ORGANOMERCURY HALIDES BY A FREE RADICAL CHAIN PROCESS
Russel, Glen A.,Hershberger, James,Owens, Karen
, p. 43 - 56 (2007/10/02)
Primary and secondary alkylmercury halides react with the salts of secondary nitroalkanes to afford tertiary nitroalkanes, mercury metal, and halide ion.The reaction is light initiated and is strongly inhibited by radical scavengers.Cyclized products resu
