70398-85-5Relevant academic research and scientific papers
Redox-Active 1D Coordination Polymers of Iron-Sulfur Clusters
Horwitz, Noah E.,Xie, Jiaze,Filatov, Alexander S.,Papoular, Robert J.,Shepard, William E.,Zee, David Z.,Grahn, Mia P.,Gilder, Chloe,Anderson, John S.
, p. 3940 - 3951 (2019/03/07)
Here we describe the combination of an archetypal redox-active metal sulfide cluster, Fe4S4, with an organic linker, 1,4-benzenedithiolate, to prepare coordination polymers containing infinite chains of Fe4S4 cl
AN ELECTRON SPIN RESONANCE INVESTIGATION OF THE RADICAL CATIONS FROM POLY(ALKYLTHIO)BENZENES
Alberti, Angelo,Pedulli, Gian Franco,Tiecco, Marcello,Testaferri, Lorenzo,Tingoli, Marco
, p. 975 - 980 (2007/10/02)
The radical cations of some poly(methylthio)- and poly(isopropylthio)-benzenes have been investigated by e.s.r. spectroscopy.Discrimination between the couplings due to the aryl and alkyl protons, when the assignment is not straightforward, has been made
SYNTHESIS OF ARYL THIOCYANATES FROM ARYL ALKYL SULPHIDES. CONVERSION OF UNACTIVATED ARYL HALIDES INTO ARYL THIOCYANATES
Testaferri, L.,Tingoli, M.,Tiecco, M.,Chianelli, D.,Montanucci, M.
, p. 263 - 268 (2007/10/02)
Aryl alkyl sulphides, easily obtained from aryl halides, can be selectively dealkylated in HMPA by treatment with sodium, sodium methanethiolate or sodium methoxide.The resulting solutions, containing the sodium arenethiolates, when treated with BrCN or ICN, afford the corresponding aryl thiocyanates in moderate to good yields.A by-product is obtained in several cases to whom the structure of ArSP(O)(NMe2)2 has been attributed.
