70402-81-2Relevant academic research and scientific papers
STEREOCHEMISTRY AT TIN AND MECHANISM OF THREE CLEAVAGE REACTIONS OF CARBON-TIN BONDS
Gielen, Marcel,Eynde, Ivan Vanden
, p. 315 - 320 (2007/10/02)
The cleavages of the trityl-tin bond by NaFe(CO)2Cp, LiBHEt3 and Ph3SnLi are not stereoselective.This is explained in terms of a one-electron transfer mechanism leading to a triorganostannyl radical which can undergo inversion before reacting with another radical to give the product.
