70412-29-2Relevant academic research and scientific papers
Thermal Isomerization of Allyl-Substituted Cyclopropenes. An Example of a Nonsynchronous Cope Rearrangement
Padwa, Albert,Blacklock, Thomas J.
, p. 2797 - 2806 (2007/10/02)
The thermal Cope rearrangement of a number of allyl-substituted cyclopropenes has been studied in mechanistic detail.Thermolysis of 1,2-diphenyl-3-allyl-3-methylcyclopropene produced an equilibrium mixture of recovered starting material (35percent), 1,3-d
Photochemistry of Cyclopropene Derivatives. 17. Competition between Side-Chain Fragmentation and Ring Opening
Padwa, Albert,Blacklock, Thomas J.,Cordova, Diana M.,Loza, Roman
, p. 5648 - 5656 (2007/10/02)
The photochemical reactions of several 3-allyl substituted diphenylcyclopropenes have been studied.Irradiation of 2-methyl-3-(1-methyl-2,3-diphenyl-2-cyclopropen-1-yl)-1-propene produced products derived from both cyclopropenyl ring opening and side-chain
Photochemistry of Cyclopropene Derivatives. Formation and Intramolecular Trapping Reactions of Vinylcarbenes
Padwa, Albert,Blacklock, Thomas J.,Loza, Roman,Polniaszek, Richard
, p. 2181 - 2189 (2007/10/02)
The intramolecular photocycloaddition reactions of a number of 3-allyl-substituted diphenylcyclopropenes have been studied.Photodimerization occured when 1,2-diphenyl-3-allylcyclopropene was irradiated in benzene.The photodimerization reaction was shown t
