70448-47-4

Upstream product

• 881894-81-1 2-azido-2-(6-benzyloxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxole-5-yl)ethanol 
• 881895-07-4 [(S)-2-Azido-2-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethoxy]-tert-butyl-diphenyl-silane 
• 881895-06-3 Trifluoro-methanesulfonic acid (R)-1-((3aR,5S,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-(tert-butyl-diphenyl-silanyloxy)-ethyl ester 
• 22529-61-9 (1R)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro(2,3-d)(1,3)dioxol-5-yl)ethane-1,2-diol 
• 369630-58-0 3-O-benzyl-6-O-tert-butyldiphenylsilyl-1,2-O-isopropylidene-α-D-glucofuranose 

Downstream Products

• 1356011-45-4 5-[(1R,2R,3S,4S)-3-O-benzyl-1,2-O-isopropylidenetetrofuranos-4-yl]tetrazole 

Relevant academic research and scientific papers

Simple and efficient conversion of N, N-dimethylhydrazones and aldehydes to nitriles

Aldehyde N,N-dimethylhydrazones undergo facile oxidative cleavage to nitriles on reaction with magnesium monoperoxyphtalate hexahydrate (MMPP).

Unusual conversion of sugar-oximes to sugar-nitriles with ruthenium catalysts

Unusual conversion of Sugar-oximes to sugar-nitriles in the presence of ruthenium catalysts such as Cl2(PCy3)2Ru=CHPh, Cl2Ru(PPh3) and RuCl3 in benzene at 60°C was reported.

New one-carbon degradative transformation of β-alkyl-β-azido alcohols

A new transformation of 2-azido-1-hydroxy-containing compounds to nitriles with one carbon less than the starting materials by oxidation was reported. The reaction can be performed under mild conditions.