70524-55-9Relevant academic research and scientific papers
Regio- and Enantioselective Formal Hydroamination of Enamines for the Synthesis of 1,2-Diamines
Yu, Lu,Somfai, Peter
supporting information, p. 8551 - 8555 (2019/05/21)
The asymmetric formal hydroamination of enamines using a CuH catalyst is reported. The method provides a straightforward and efficient approach to the synthesis of chiral 1,2-dialkyl amines in good yields with high levels of enantioselectivities for a broad range of substrates, and should have significant value for the preparation of molecules bearing a 1,2-diamine motif.
Dramatic synergistic effects between hydroquinone and resorcinol derivatives for the organocatalyzed reduction of dioxygen by diethylhydroxylamine
Lebeuf, Raphael,Nardello-Rataj, Veronique,Aubry, Jean-Marie
supporting information, p. 866 - 868 (2014/01/06)
Diethylhydroxylamine reduces dioxygen in the presence of catalytic amounts of hydroquinone. A great improvement is achieved by adding resorcinol derivatives as co-catalysts. Though the formation of heterodimers does not seem to be the sole cause of the synergy, such products constitute a new class of powerful organocatalysts for dioxygen scavenging. The Royal Society of Chemistry.
