70524-91-3Relevant academic research and scientific papers
Lewis Acid Promoted Decomposition of Unsaturated α-Diazo Ketones. 3. Stereochemical Consequences of Polyolefinic Cyclizations Initiated by the α-Diazo Ketone Functionality
Smith, Amos B.,Dieter, R. Karl
, p. 2017 - 2022 (2007/10/02)
This report presents the stereochemical consequences of polyolefinic cyclizations initiated by Lewis acid decomposition of α-diazo ketones.Three diazo ketones (1, 2, and 5) were examined; each was found to undergo a nonstereospecific process leading eithe
