70531-77-0Relevant academic research and scientific papers
Palladium-catalyzed silylene-1,3-diene [4 + 1] cycloaddition with use of (aminosilyl)boronic esters as synthetic equivalents of silylene
Ohmura, Toshimichi,Masuda, Kohei,Takase, Ichiro,Suginome, Michinori
supporting information; experimental part, p. 16624 - 16625 (2010/02/16)
(Chemical Equation Presented) Silylboronic esters bearing a dialkylamino group on the silicon atoms reacted with 1,3-dienes in the presence of a palladium catalyst to give silacyclopent-3-enes (i.e., 2,5-dihydrosiloles) in high yields via efficient silyle
