70551-63-2Relevant academic research and scientific papers
Synthesis and properties of 1,3-bis[(2-bromo)benzene]triazene and its binuclear silver complex
Xie, Qian-Ya,Liu, Wei-Xia,Zhan, Shu-Zhong,Wei, Xiao-Lan
, p. 630 - 636 (2020)
The reaction of 2-bromoaniline with sodium nitrite affords a triazenido compound, 1,3-bis[(2-bromo)benzene]triazene (HL). Spectroscopic investigations show that HL bears a high selectivity for silver(I) ion in the presence of other metal ions. In the pres
Synthesis and properties of amphiphilic photoresponsive gelators for aromatic solvents
Rajaganesh, Ramanathan,Gopal, Anesh,Mohan Das, Thangamuthu,Ajayaghosh, Ayyappanpillai
supporting information; experimental part, p. 748 - 751 (2012/03/26)
A sugar-based photoresponsive supergelator, N-glycosylazobenzene that shows selective gelation of aromatic solvents is described. The partial trans - cis isomerization of the azobenzene moiety allows photoinduced chopping of the entangled gel fibers to short fibers, resulting in controlled fiber length and gel - sol transition. The gelator is useful for the selective removal of toxic aromatic solvents from water.
A ligand-free copper (1) catalysed intramolecular N-arylation of diazoaminobenzenes in PEG-water: An expeditious protocol towards regiospecific 1-aryl benzotriazoles
Mukhopadhyay, Chhanda,Tapaswi, Pradip Kumar,Butcher, Ray J.
supporting information; experimental part, p. 4720 - 4729 (2010/11/17)
An efficient and highly versatile method for the synthesis of diverse regiospecific 1-arylbenzotriazoles being important medicinal scaffolds, by the copper (1) catalysed intramolecular N-arylation of diazoaminobenzenes of 2-haloaryldiazonium salts in PEG-water has been developed. A very simple reaction protocol, large number of substrate affordability and excellent yields are the main features of this methodology.
