705932-79-2Relevant academic research and scientific papers
Transition-Metal-Catalyzed Aldehydic C-H Activation by Azodicarboxylates
Lee, Daesung,Otte, Ryan D.
, p. 3569 - 3571 (2004)
Rhodium acetate-catalyzed hydroacylation between aldehydes and an activated form of N=N bond was achieved under mild conditions to provide efficient access to a variety of hydrazino imides. Good selectivity for the aldehydic C-H activation relative to the ene-type reaction was observed with aldehydes having unsaturation both at terminal and internal positions.
Use of N-N bond stereodynamics in ring-closing metathesis to form medium-sized rings and macrocycles
Yi, Jin Kim,Lee, Daesung
, p. 4351 - 4353 (2007/10/03)
(Chemical Equation Presented) A unique strategy based on double ring-closing metathesis for the formation of a 14-membered macrocyclic enamide has been developed. This strategy hinges upon the well-known stereodynamic and conformational behavior of N-substituted diacylhydrazines, which promotes an effective ring-closing metathesis of hydrazine-derived dienes and enynes to form 8- to 14-membered rings.
