705933-36-4Relevant academic research and scientific papers
A useful synthetic equivalent of an acetone enolate
Maslak, Veselin,Tokic-Vujosevic, Zorana,Ferjancic, Zorana,Saicic, Radomir N.
experimental part, p. 6709 - 6711 (2010/01/18)
2-Methoxymethoxy-3-chloropropene derived organometallics act as synthetic equivalents of an acetone enolate. Indium-promoted reaction of this reagent with aldehydes affords aldol adducts in moderate to excellent yields. When the reaction was performed wit
Tris(pentafluorophenyl)silyl enol ethers: Synthesis and aldol reactions
Dilman, Alexander D.,Belyakov, Pavel A.,Korlyukov, Alexander A.,Tartakovsky, Vladimir A.
, p. 3741 - 3744 (2007/10/03)
Silyl enol ethers bearing three pentafluorophenyl groups at the silicon atom are described. These compounds undergo uncatalyzed aldol reactions with aliphatic, α,β-unsaturated, and aromatic aldehydes. The observed reactivity is analyzed in terms of the Le
