70599-87-0

Basic information

• Product Name: 1-nitro-3-propoxybenzene
• Synonyms: Benzene, 1-nitro-3-propoxy-
• CAS NO: 70599-87-0
• Molecular Formula: C₉H₁₁NO₃
• Molecular Weight: 181.1885
• Mol File: 70599-87-0.mol

Chemical Properties

• Boiling Point: 285.7°C at 760 mmHg
• Flash Point: 129°C
• Density: 1.144g/cm³
• Vapor Pressure: 0.00476mmHg at 25°C
• Refractive Index: 1.528
• CAS DataBase Reference: 1-nitro-3-propoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-nitro-3-propoxybenzene(70599-87-0)
• EPA Substance Registry System: 1-nitro-3-propoxybenzene(70599-87-0)

Safety Data

• Hazardous Substances Data: 70599-87-0(Hazardous Substances Data)

Upstream product

• 554-84-7 meta-nitrophenol 
• 106-94-5 propyl bromide 
• 107-08-4 1-iodo-propane 

Downstream Products

• 4469-79-8 3-propoxyaniline 
• 98772-19-1 6-Oxo-2-(3-propoxy-phenylamino)-1,6-dihydro-pyrimidine-5-carboxylic acid 
• 98771-68-7 6-Oxo-2-(3-propoxy-phenylamino)-1,6-dihydro-pyrimidine-5-carboxylic acid ethyl ester 
• 860735-50-8 N,N-dimethyl-3-propoxy-aniline 
• 55792-52-4 acetic acid-(3-propoxy-anilide) 
• 857591-30-1 4-nitro-3-propoxy-aniline 
• 855839-72-4 Propyl-(6-nitro-3-hydroxy-phenyl)-aether 
• 130349-21-2 acetic acid-(2-nitro-5-propoxy-anilide) 
• 860578-16-1 acetic acid-(4-nitro-3-propoxy-anilide) 
• 113501-99-8 2-nitro-5-propoxyaniline 
• 59731-89-4 N-Aethyl-m-propyloxyanilin 

Relevant articles and documents

[Cp?RhCl2]2-catalyzed alkyne hydroamination to 1,2-dihydroquinolines

[Cp?RhCl2]2 catalyzes the formation of 1,2-dihydroquinolines from the reaction of two terminal alkynes and an aniline. This reaction is believed to proceed via an alkyne hydroamination followed by an alkyne insertion.

An insight into the extraction of transition metal ions by picolinamides associated with intramolecular hydrogen bonding and rotational isomerization

The clear connection between molecular structures of N-substituted picolinamides and extraction behaviour has been rationalized by highlighting the relationship between intramolecular hydrogen bonding and rotational isomerism. To this aim aromatic pyridine-2,6-dicarboxamides 1a-1c with N-substitution and their analogues 3a and 3b containing intramolecular hydrogen bonds were designed and synthesized. The results from the liquid-liquid extraction towards some representative transition metal picrates including Ag+, Hg 2+, Pb2+, Cd2+, Zn2+, Cu 2+, Co2+ and Ni2+ salts demonstrated that the higher selectivity and efficiency towards Hg2+ (88.6-95.4%) over other metal cations stem mainly from N-substitution via disruption of intramolecular H-bonding. X-ray structural analysis, and ordinary and variable-temperature proton and carbon NMR experiments provided supporting information for expounding the difference in extraction ability among these ligands, particularly the importance of N-substitution that leads to the formation of rotamers affecting the extraction process.