70600-66-7Relevant academic research and scientific papers
Phosphine-dependent selective cross-dimerization between terminal alkylacetylene and silylacetylene by iridium(I) guanidinate complex-phosphine system
Ogata, Kenichi,Oka, Oji,Toyota, Akinori,Suzuki, Noriyuki,Fukuzawa, Shin-Ichi
, p. 2663 - 2666 (2008)
The new iridium(I)-guanidinate complex served as an efficient catalyst for phosphine-dependent selective cross-dimerization between silylacetylene and terminal alkyl- or arylacetylene. Especially, in case of cross-dimerization between silylacetylene and alkylacetylene, E/Z selectivity of resulting enynes could be controlled by changing phosphine.
