7061-41-8Relevant academic research and scientific papers
Anomalous Reaction of Arylmalononitriles with Nitric Acid. Para-Directing Nature of Dicyanomethyl Group and a Through-Ring Nitro/aci-Nitro Tautomerism of 4-Nitrophenylmalononitrile
Suzuki, Hitomi,Koide, Hideki,Ogawa, Takuji
, p. 501 - 504 (2007/10/02)
Phenylmalononitrile reacts with nitric acid in dichloromethane at room temperature to afford 1,2-bis(4-nitrophenyl)-1,1,2,2-tetracyanoethane as an initial product, which readily suffers oxidative cleavage to give 4-nitrobenzoyl cyanide.Contrary to common
CARBON-CARBON BOND FORMATION BY COORDINATION OF CARBOCATIONS WITH CARBANIONS.
Arnett, Edward M.,Troughton, E. B.
, p. 3299 - 3302 (2007/10/02)
Direct attack of resonance-stabilized carbenium ions and carbanions can be regulated to provide a wide range of rates and equilibria for the study of carbon-carbon bond formation.
